Place the pork chops in the water and mix in the salt and peppercorns. Let this sit for 12 to 24 hours.
Bring the pork chops to room temperature as you preheat the oven to 350 degrees F. Spread the oil on a baking pan or on the bottom of a Dutch oven or cast iron skillet.
Mix the seasonings with the brown sugar. Rub it on the surface of each pork chop. Place the chops on the oiled pan or skillet.
Cook the pork chops for 20 minutes, or until the internal temperature is 135 F.
Turn on the broiler and broil each side of the pork chops for 2 to 3 minutes. Make sure the internal temperature is 140 degrees F. The pork will rise 5 more degrees while resting.